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So far only norharman and harman -carbolines have been reported in coffee (any reference in this review to -carbolines refers to only these two)

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Pantotheenzuur (calcium-D-pantothenaat)

Here, the authors report a rhodium/chiral phosphoric acid cooperative catalysis for the three-component reaction of -diazo ketones with alcohols and 1,3,5-triazines via imine chiral activation.