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Cancer Res 48:27642767 Clark O, Park I, Di Florio A et al (2015) Oxovanadium-based inhibitors can drive redox-sensitive cytotoxicity in neuroblastoma cells and synergise strongly with buthionine sulfoximine

This has two effects: First, ethanol and acetaldehyde are inefficiently metabolized, and, second, electrons passing through the mitochondrial electron transport chain are diverted into forming harmful ROS, mainly superoxide (Hoek et al

GSSG and GSH from mammals are the molecular analogs of TS 2 and T(SH) 2 from T

[DOI] [PubMed] [Google Scholar] Prakash G., Shokr A., Willemen N., Bashir S.M., Shin S.R., Hassan S

For instance, daily administration of antioxidant grape seed proanthocyanidin extract at Zeitgeber time 0 (ZT0) can restore the disrupted diurnal rhythms of catalytic activity, GPX1 activity, and GSH levels in rats subjected to a cafeteria diet, whereas treatment at ZT12 fails to achieve this effect [278]