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Remarkably, the antioxidant effects of thiamine, including Nrf2 activation, are observed even when the thiamine disulfide forms which should decrease cellular redox potential are administered (206)

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In biological systems, redox reactions occur through the transfer of electrons from reduced donor molecules (including NADPH and thiols in reduced glutathione (GSH) and the amino acid cysteine found in many proteins) to acceptor molecules (such as NADP+ and disulfide bonds in cysteine, the oxidized dimeric form of cysteine) 5