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This again suggests the critical role of peroxynitriterather than LPOas the primary cause of oxidative damage to mitochondrial DNA 18 and protein nitration, which are central mechanisms of toxicity (Fig

Then, another N -centred [2,3]-sigmatropic rearrangement of INT2-Se forms para -amination intermediate INT3-Se via TS2-Se (with a barrier of 4.4 kcal mol 1 , see path 1-Se )

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