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Mayo Clinic advises against the use of unapproved substances due to unknown purity and lack of regulatory oversight [my.clevelandclinic.org], [mayoclinic.org]

Stomach disorders

Of note, monomethyl fumarate, a metabolite of the MS medication dimethyl fumarate, is also able to stimulate the Hcar2 receptor, and this mediates at least part of its therapeutic response in a model of MS [60,61,62]

Yes, both are prohibited

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Short intravenous administration of LPS in humans has induced a storm of cardiovascular hormonal and cytokine markers (113), suggesting that the bacteria increase the cardiovascular risk