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Cysteine plays a significant role by contributing the essential redox-active thiol group central to its multifaceted functions
10.1007/s11910-012-0264-9 135 WoodhamsS
Glucocorticoids levels are low after the onset of darkness and rise after the middle of the night concomitantly with a decrease in melatonin levels

Alpha-Arbutin complements this pathway by refining uneven pigmentation while preserving barrier integrity and skin balance
[DOI] [PMC free article] [PubMed] [Google Scholar] PRISMA [WWW Document], n.d