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Unlike the other compounds discussed, MOTS-C is a mitochondrial-derived peptide, a 16-amino-acid sequence encoded within the mitochondrial genome itself

An extensively utilized strategy for chemical ligation and peptide stapling involves the Cu(I)-catalyzed azidealkyne 1,3-dipolar Huisgen cycloaddition, commonly known as the CuAAC click reaction or the strain-promoted azidealkyne cycloaddition (SPAAC) (see Section )

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That dual mechanism matters